The ZnO/CdTe core-shell NW arrays were dipped in a saturated CdCl

The ZnO/CdTe core-shell NW arrays were dipped in a saturated CdCl2:methanol solution for 30 min and then annealed under argon atmosphere for 1 h at different annealing temperatures in the range of 300°C to 500°C.

FESEM, XRD, Raman scattering, PL, and absorption measurements The structural properties of the ZnO/CdTe core-shell NW arrays were investigated by field-emission scanning electron microscopy (FESEM), high-resolution transmission electron microscopy (HRTEM), X-ray diffraction (XRD) measurements, and Raman scattering measurements. FESEM images were recorded with a ZEISS Ultra 55 microscope (Oberkochen, Germany). this website HRTEM specimens were prepared by dispersing ZnO/CdTe core-shell NWs kept in an ethanol solution on a copper grid. HRTEM images were recorded with a JEOL JEM-2010 microscope (Tokyo, Japan) operating at 200 kV. XRD patterns were collected with a PanAlytical diffractometer (Almelo, The Netherlands) using CuKα radiation according to the Bragg-Brentano configuration. The texture of the CdTe shell was quantitatively analyzed from the Kα1 component in the framework of the Harris method by determining both the degree of preferred orientation and texture coefficients [40, 41]. The θ-2θ XRD measurements were performed in the range of 20° to 100° (in

2θ scale). Seven CdTe diffraction peaks SB202190 were taken into account for the texture analysis: (111), (220), (311), (400), (331), (422), and (531). The (511) diffraction peak was excluded from the texture analysis, as being superimposed with the (333) diffraction peak. The intensity of each CdTe diffraction peak was precisely determined by pseudo-Voigt fits, and their deconvolution with other SnO2 or ZnO diffraction peaks was carefully achieved when required. The 00-041-1445, 00-036-1451, and 00-0150770 files of the International Center for Diffraction Data (ICDD) were used for SnO2, ZnO, dipyridamole and CdTe, respectively. Absorption measurements were performed with a UV-visible-NIR Perkin Elmer Lambda 950 spectrophotometer (Waltham, MA, USA). An integrating sphere was used for light-harvesting

efficiency measurements by determining the total optical transmittance and reflectance. The 5 K PL measurements were achieved in a helium flow cryostat by using a frequency-doubled argon laser operating at 244 nm. The 5 K PL spectra were analyzed by using a spectrometer equipped with a 600-line/mm grating and ABT-737 mouse detected with a liquid-nitrogen cooled charge-coupled device (i.e., CCD detector). The excitation power was varied by using an optical attenuator. For all of the PL spectra, the spot size was about 100 μm. Raman measurements were performed with an argon laser operating at 514.5 nm, and the scattered light was analyzed using a Jobin-Yvon T64000 triple spectrometer (Palaiseau, France) equipped with a CCD detector.

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